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51.
采用酸处理方法对CoPd/TiO2催化剂进行改性,并将酸改性催化剂用于温和条件下CH4-CO2梯阶转化直接合成C2含氧化合物(乙酸和乙醇)的反应。在150~300℃考察了浸酸方式和不同种类酸处理对催化剂活性和选择性的影响。采用X射线衍射(XRD)、X射线光电子能谱(XPS)、NH3程序升温脱附(NH3-TPD)和N2吸附对催化剂进行了表征。结果表明,酸改性明显提高了CoPd/TiO2上C2含氧化合物的生成速率和选择性。浸酸方式对催化剂性能和结构有显著影响,先用酸浸渍载体然后再浸渍活性金属所得催化剂具有更高的活性。在H3PO4、HNO3和HCl中,H3PO4浸渍的催化剂活性最佳,在150℃时C2含氧化合物(乙酸和乙醇)的生成速率为3365 μg/(g·h),选择性达到91%。 相似文献
52.
Meiling He Yinzi Cheng Linli Shen Huiling Zhang Chenyang Shen Weidong Xiang Xiaojuan Liang 《Journal of the American Ceramic Society》2019,102(3):1090-1100
CsPbX3 (X = Cl, Br, I) perovskite quantum dots (QDs) represent bright and tunable photoluminescence, it is regrettable that the air instability and poor water resistant properties prevent their application in optoelectronic devices. At the same time, the toxicity of lead is also a major factor restricting its development. As a consequence, we demonstrate the partial replacement of Pb with Mn through conventional melt-quenching and heat-treatment method preparation of Mn-doped CsPb(Cl/Br)3 QD glass. Mn-doped CsPb(Cl/Br)3 QD glass exhibits high luminescent intensity like QDs. It is important that Mn-doped CsPb(Cl/Br)3 QD glass with Dual-Color maintained the same lattice structure like Mn-doped CsPb(Cl/Br)3 QDs, and highly homogeneous spectral characteristics of Mn luminescence. The intensity and position of this Mn-related emission are also tunable by altering the experimental parameters, such as the Pb-to-Mn feed ratio, annealing temperature. More importantly, the as-prepared orange Mn-doped CsPb(Cl/Br)3 QD glass was employed to fabricate white LEDs combined with a commercial Ce3+:Y3Al5O12 phosphor-in-glass (Ce-PiG) on top of a InGaN blue chip. And the constructed WLEDs generate a warm white with an optimal luminous efficacy (LE) of 67.00 lm/W, a high CRI of 81.4, and a low CCT of 4902 K. 相似文献
53.
水合物的存在会显著影响能源土的刚度、峰值强度与剪胀性。针对已有能源土模型的不足,结合边界面模型的建模思想,构建一个新的能源土边界面模型,模型参数较少,能够恰当反映能源土的应力-应变关系。计算能源土变形问题的核心在于正确积分塑性本构方程,应用完全隐式回退Euler算法,建立模型应力及塑性内变量的更新公式,并给出显式的一致性切线模量表达式。基于ABAQUS软件提供的二次开发接口,编写模型的用户材料子程序,应用已有试验数据验证程序正确性。最后应用开发的子程序对能源土的平面应变试验进行模拟,分析水合物饱和度对剪切带倾角与孔隙比的影响。 相似文献
54.
Guo Jianmei Liang Jia Hui Shi Kai Yang Dingyu Zhang Jingsong Czarnecki Krzysztof Ganesh Vijay Yu Huiqun 《Software and Systems Modeling》2019,18(2):1447-1466
Software and Systems Modeling - A key challenge to software product line engineering is to explore a huge space of various products and to find optimal or near-optimal solutions that satisfy all... 相似文献
55.
Yong Li Juan Wang HuiXing Huang Jia Wang Mi Zhang MMeng Liang 《Advanced Powder Technology》2019,30(8):1442-1449
The electronic conductivity enhanced has been extensively studied and reported in lithium iron phosph-ate (LiFePO4). However, only few existing literatures are available for researchers to enhance simultaneously the ion and electronic conductivity of LiFePO4. Herein, we disclose that the LiFePO4 is co-coated with novel GdPO4 and Carbon via a hydrothermal-assisted solid-phase method, contributing to particle size and dispersibility. What surprising is that the ionic and electronic conductivity of the material is significantly enhanced, and the interfacial side reaction is effectively inhibited between the materials and the electrolytes. The diverse proportions of the mixed coating (LiFePO4/C&xGdPO4 (x = 0, 1 wt%, 2 wt%, 3 wt%, 4 wt%)) are synthesized compared with bare LiFePO4. The experimental results suggest that LiFePO4/C&0.03GdPO4 exhibits the most excellent electrochemical performance. There is discharge capacity of 158, 148.8, 141.6, 134.9, 121.8, 104.9, and 86.7mAh/g at 0.1, 0.2, 0.5, 1, 2, 5, and 10 C rates, respectively. 相似文献
56.
针对仿人机器人步行过程中存在的机器人关节角加速度约束影响控制性能的问题,提出一种考虑关节角加速度约束的仿人机器人偏摆力矩控制方法.该方法充分考虑了双臂在摆动过程中对偏摆力矩的影响,根据力矩平衡条件得到需要抵消的偏摆力矩的大小与方向,将偏摆力矩的控制问题转化为带约束条件的二次规划问题,并设计了一种在线变步长迭代算法计算得到优化后的双臂摆动轨迹.实验表明,该方法能有效抵消机器人步行中产生的偏摆力矩,避免控制过程中的"削峰"现象,有效提高机器人的步行稳定性. 相似文献
57.
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59.
Gong Zhiqiang Zhang Yanhu Fu Hao Zhou Yuhua Liang Hongyu Ji Jinghu 《International Journal of Mechanics and Materials in Design》2021,17(4):969-986
International Journal of Mechanics and Materials in Design - Conform and non-conformal contact problem in the face of piezoelectric motors can be hard to grasp, especially both the friction drive... 相似文献
60.
A mechanistic model that considers particle dynamics and their effects on surface emissions and sorptions was developed to predict the fate and transport of phthalates in indoor environments. A controlled case study was conducted in a test house to evaluate the model. The model‐predicted evolving concentrations of benzyl butyl phthalate in indoor air and settled dust and on interior surfaces are in good agreement with measurements. Sensitivity analysis was performed to quantify the effects of parameter uncertainties on model predictions. The model was then applied to a typical residential environment to investigate the fate of di‐2‐ethylhexyl phthalate (DEHP) and the factors that affect its transport. The predicted steady‐state DEHP concentrations were 0.14 μg/m3 in indoor air and ranged from 80 to 46 000 μg/g in settled dust on various surfaces, which are generally consistent with the measurements of previous studies in homes in different countries. An increase in the mass concentration of indoor particles may significantly enhance DEHP emission and its concentrations in air and on surfaces, whereas increasing ventilation has only a limited effect in reducing DEHP in indoor air. The influence of cleaning activities on reducing DEHP concentration in indoor air and on interior surfaces was quantified, and the results showed that DEHP exposure can be reduced by frequent and effective cleaning activities and the removal of existing sources, though it may take a relatively long period of time for the levels to drop significantly. Finally, the model was adjusted to identify the relative contributions of gaseous sorption and particulate‐bound deposition to the overall uptake of semi‐volatile organic compounds (SVOCs) by indoor surfaces as functions of time and the octanol‐air partition coefficient (Koa) of the chemical. Overall, the model clarifies the mechanisms that govern the emission of phthalates and the subsequent interactions among air, suspended particles, settled dust, and interior surfaces. This model can be easily extended to incorporate additional indoor source materials/products, sorption surfaces, particle sources, and room spaces. It can also be modified to predict the fate and transport of other SVOCs, such as phthalate‐alternative plasticizers, flame retardants, and biocides, and serves to improve our understanding of human exposure to SVOCs in indoor environments. 相似文献